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用于检测农药福美双的银纳米线作为表面增强拉曼散射(SERS)基底的合成

Synthesis of silver nanowires as a SERS substrate for the detection of pesticide thiram.

作者信息

Zhang Li, Wang Bin, Zhu Guang, Zhou Xia

机构信息

School of Biological and Chemical Engineering, Anhui Key Laboratory of Spin Electron and Nanomaterials, Suzhou University, Suzhou 234000, PR China.

School of Biological and Chemical Engineering, Anhui Key Laboratory of Spin Electron and Nanomaterials, Suzhou University, Suzhou 234000, PR China; School of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, PR China.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2014 Dec 10;133:411-6. doi: 10.1016/j.saa.2014.06.054. Epub 2014 Jun 16.

Abstract

Silver nanowires with uniform diameters have been synthesized via the rapid sulfide mediated polyol method. The morphology, structure, and properties of as-prepared samples are characterized by UV-Visible spectroscopy, field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD), respectively. The mechanism of as-prepared Ag nanowires is provided and discussed. Moreover, as-prepared Ag nanowires are used as a Surface-Enhanced Raman Scattering (SERS) substrate to detect thiram pesticide. The results show that this substrate based on Ag nanowires exhibits high sensitivity and reproducibility for the thiram detection.

摘要

通过快速硫化物介导的多元醇法合成了具有均匀直径的银纳米线。分别采用紫外可见光谱、场发射扫描电子显微镜(FESEM)和X射线衍射(XRD)对所制备样品的形貌、结构和性能进行了表征。提供并讨论了所制备银纳米线的形成机理。此外,将所制备的银纳米线用作表面增强拉曼散射(SERS)基底来检测福美双农药。结果表明,这种基于银纳米线的基底对福美双检测具有高灵敏度和重现性。

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