过氧壬二酸（过氧酸）：一种稳定的过氧酸，可用于氧化溴化蒽-9,10-二酮中的氨基。

Nonanebis(peroxoic acid): a stable peracid for oxidative bromination of aminoanthracene-9,10-dione.

机构信息

Department of Dyestuff Technology, Institute of Chemical Technology, N. P. Marg, Matunga, Mumbai - 400019, India. Tel.: 91-22-33612708.

出版信息

Beilstein J Org Chem. 2014 Apr 24;10:921-8. doi: 10.3762/bjoc.10.90. eCollection 2014.

DOI:10.3762/bjoc.10.90

PMID:24991241

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4077418/

Abstract

A new protocol for the oxidative bromination of aminoanthracene-9,10-dione, which is highly deactivated towards the electrophilic substitution is investigated. The peracid, nonanebis(peroxoic acid), possesses advantages such as better stability at room temperature, it is easy to prepare and non-shock sensitiv as compared to the conventional peracids. The present protocol has a broad scope for the bromination of various substituted and unsubstituted aminoanthracene-9,10-diones.

摘要

研究了一种新的协议，用于对高度失活的氨基蒽-9,10-二酮进行氧化溴化，该试剂对亲电取代反应不活泼。过酸，壬烷双（过氧酸），与传统过酸相比，具有更好的室温稳定性、易于制备和非冲击敏感性等优点。本协议适用于各种取代和未取代的氨基蒽-9,10-二酮的溴化。