基于烯烃交叉复分解反应的新型合成部分保护的 L-阿米糖和全保护的 L-棉子糖衍生物。
Olefin cross metathesis based de novo synthesis of a partially protected L-amicetose and a fully protected L-cinerulose derivative.
机构信息
Institut für Chemie, Organische Synthesechemie, Universität Potsdam, Karl-Liebknecht-Straße 24-25, 14476 Potsdam-Golm, Germany.
出版信息
Beilstein J Org Chem. 2014 May 6;10:1023-31. doi: 10.3762/bjoc.10.102. eCollection 2014.
Abstract
Cross metathesis of a lactate derived allylic alcohol and acrolein is the entry point to a de novo synthesis of 4-benzoate protected L-amicetose and a cinerulose derivative protected at C5 and C1.
摘要
乳酸烯丙基醇与丙烯醛的交叉复分解反应是从头合成 4-苯甲酸酯保护的 L-阿米醇和 C5 和 C1 位保护的西尼洛醇衍生物的切入点。
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