四丁基鏻离子作为层状化合物的新型溶胀/剥离剂。

Tetrabutylphosphonium ions as a new swelling/delamination agent for layered compounds.

作者信息

Geng Fengxia, Ma Renzhi, Yamauchi Yusuke, Sasaki Takayoshi

机构信息

International Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.

出版信息

Chem Commun (Camb). 2014 Sep 7;50(69):9977-80. doi: 10.1039/c4cc03736g.

DOI:10.1039/c4cc03736g

PMID:25034032

Abstract

The swelling and exfoliation behavior of protonated layered oxides using an organo-phosphonium base, tetrabutylphosphonium hydroxide (TBPOH), was examined for the first time. The action of the aqueous solution induced massive interlayer expansion up to ~100-fold. The swollen crystals were immediately broken and completely exfoliated into unilamellar nanosheets in 1-2 h by shaking.

摘要

首次研究了使用有机鏻碱四丁基氢氧化鏻（TBPOH）对质子化层状氧化物的膨胀和剥离行为。水溶液的作用导致层间大量膨胀，膨胀倍数高达约100倍。通过摇晃，膨胀后的晶体在1-2小时内立即破碎并完全剥离成单层纳米片。