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修饰的铕掺杂氧化钇纳米颗粒作为用于灵敏检测吡哆醇的猝灭型发光探针。

Modified Eu-doped Y2 O3 nanoparticles as turn-off luminescent probes for the sensitive detection of pyridoxine.

作者信息

Zobeiri Eshagh, Bayandori Moghaddam Abdolmajid, Gudarzy Forugh, Mohammadi Hadi, Mozaffari Shahla, Ganjkhanlou Yadolah

机构信息

Department of Chemistry, Islamic Azad University, Qeshm Branch, Iran.

出版信息

Luminescence. 2015 May;30(3):290-5. doi: 10.1002/bio.2727. Epub 2014 Jul 25.

Abstract

Europium-doped yttrium oxide nanoparticles (Y2 O3 :Eu NPs) modified by captopril were prepared in aqueous solution. In this study, we report the effect of pyridoxine hydrochloride on the photoluminescence intensity of Y2 O3 :Eu NPs in pH 7.2 buffer solution. By increasing the pyridoxine concentration, the luminescence intensity of Y2 O3 :Eu NPs is quenched. The results show that this method demonstrates high sensitivity for pyridoxine determination. A linear relationship is observed between 0.0 and 62.0 μM with a correlation coefficient of 0.995 and a detection limit of 0.023 μM.

摘要

在水溶液中制备了用卡托普利修饰的铕掺杂氧化钇纳米颗粒(Y2O3:Eu NPs)。在本研究中,我们报道了盐酸吡哆醇对pH 7.2缓冲溶液中Y2O3:Eu NPs光致发光强度的影响。通过增加吡哆醇浓度,Y2O3:Eu NPs的发光强度被猝灭。结果表明,该方法对吡哆醇测定具有高灵敏度。在0.0至62.0 μM之间观察到线性关系,相关系数为0.995,检测限为0.023 μM。

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