一种由二芳基乙炔方便地串联一锅法合成给体-受体型三亚苯2,3-二羧酸酯。
A convenient tandem one-pot synthesis of donor-acceptor-type triphenylene 2,3-dicarboxylic esters from diarylacetylene.
作者信息
Feng Chun, Tian Xian-Li, Zhou Jing, Xiang Shi-Kai, Yu Wen-Hao, Wang Bi-Qin, Hu Ping, Redshaw Carl, Zhao Ke-Qing
机构信息
College of Chemistry and Material Sciences, Sichuan Normal University, Chengdu, 610068, P.R. China.
出版信息
Org Biomol Chem. 2014 Sep 28;12(36):6977-81. doi: 10.1039/c4ob01503g.
PMID:25103209
Abstract
A tandem one-pot method for the direct synthesis of polysubstituted triphenylene 2,3-dicarboxylic esters with different substitution patterns was developed by enyne metathesis of diarylacetylene, followed by Diels-Alder, aromatization and a cyclization cascade.
摘要
通过二芳基乙炔的烯炔复分解反应，随后进行狄尔斯-阿尔德反应、芳构化和环化级联反应，开发了一种串联一锅法直接合成具有不同取代模式的多取代三亚苯-2,3-二羧酸酯。
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