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中国中部湖北省工业走廊大气降尘中的多环芳烃

Polycyclic aromatic hydrocarbons (PAHs) in atmospheric dustfall from the industrial corridor in Hubei Province, Central China.

作者信息

Zhang Jiaquan, Qu Chengkai, Qi Shihua, Cao Junji, Zhan Changlin, Xing Xinli, Xiao Yulun, Zheng Jingru, Xiao Wensheng

机构信息

School of Environmental Science and Engineering, Hubei Key Laboratory of Mine Environmental Pollution Control and Remediation, Hubei Polytechnic University, Huangshi, 435003, China.

Key Laboratory of Aerosol Chemistry and Physics, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an, 710075, China.

出版信息

Environ Geochem Health. 2015 Oct;37(5):891-903. doi: 10.1007/s10653-014-9647-y. Epub 2014 Sep 12.

Abstract

Thirty atmospheric dustfall samples collected from an industrial corridor in Hubei Province, central China, were analyzed for 16 USEPA priority polycyclic aromatic hydrocarbons (PAHs) to investigate their concentrations, spatial distributions, sources, and health risks. Total PAH concentrations (ΣPAHs) ranged from 1.72 to 13.17 µg/g and averaged 4.91 µg/g. High molecular weight (4-5 rings) PAHs averaged 59.67% of the ΣPAHs. Individual PAH concentrations were not significantly correlated with total organic carbon, possibly due to the semi-continuous inputs from anthropogenic sources. Source identification studies suggest that the PAHs were mainly from motor vehicles and biomass/coal combustion. The incremental lifetime cancer risks associated with exposure to PAHs in the dustfall ranged from 10(-4) to 10(-6); these indicate potentially serious carcinogenic risks for exposed populations in the industrial corridor.

摘要

对从中国中部湖北省某工业走廊采集的30个大气降尘样本进行了分析,以检测16种美国环境保护局(USEPA)优先控制的多环芳烃(PAHs),从而调查其浓度、空间分布、来源及健康风险。总多环芳烃浓度(ΣPAHs)范围为1.72至13.17 µg/g,平均为4.91 µg/g。高分子量(4 - 5环)多环芳烃平均占ΣPAHs的59.67%。单个多环芳烃浓度与总有机碳无显著相关性,这可能是由于人为源的半连续输入所致。源识别研究表明,多环芳烃主要来自机动车以及生物质/煤炭燃烧。与降尘中多环芳烃暴露相关的终生增量癌症风险范围为10(-4)至10(-6);这些表明工业走廊中暴露人群存在潜在的严重致癌风险。

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