Department of Physics and Astronomy, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai 200240, China.
Advanced Photon Source, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, USA.
Nat Commun. 2014 Sep 23;5:5014. doi: 10.1038/ncomms6014.
To date, there is still no general consensus on the fundamental principle that governs glass transition. Colloidal suspensions are ordinarily utilized as model systems to study the dynamical arrest mechanisms in glass or gels. Here, we tackle the problem using athermal granular particles. Slow dynamics and structural evolution of granular packing upon tapping are monitored by fast X-ray tomography. When the packing are wet and short-range attractive interactions exist, we find a large amount of locally favoured structures with fivefold symmetry, which bear great structural similarity to colloidal gels. In addition, these structures are almost absent in dry packing with similar packing fractions. The study leads strong support for the geometrical frustration mechanism for dynamic arrest in both thermal and athermal systems with attractive interactions. It also suggests nontrivial structural mechanism, if exists, for dynamic arrest in systems with purely repulsive interactions.
迄今为止,对于控制玻璃化转变的基本原理仍没有普遍共识。胶体悬浮液通常被用作模型体系来研究玻璃或凝胶中的动力学弛豫机制。在这里,我们使用非热颗粒来解决这个问题。通过快速 X 射线断层扫描监测敲击时颗粒堆积的慢动力学和结构演化。当堆积物湿润且存在短程吸引力时,我们发现存在大量具有五重对称性的局部有利结构,这些结构与胶体凝胶具有很大的结构相似性。此外,在具有相似堆积分数的干燥堆积中,这些结构几乎不存在。这项研究为热和非热系统中具有吸引力的相互作用的动力学弛豫的几何阻挫机制提供了有力支持。它还表明,如果存在的话,对于具有纯排斥相互作用的系统中的动力学弛豫存在非平凡的结构机制。