• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Stereoselective syntheses of cryptocarya diacetate and all its stereoisomers in optically pure forms.

作者信息

Yamauchi Satoshi, Nishimura Hiroki, Nishiwaki Hisashi

机构信息

a Faculty of Agriculture , Ehime University , Matsuyama , Japan.

出版信息

Biosci Biotechnol Biochem. 2015;79(1):16-24. doi: 10.1080/09168451.2014.962476. Epub 2014 Sep 25.

DOI:10.1080/09168451.2014.962476
PMID:25253635
Abstract

Cryptocarya diacetate and each of its stereoisomers were stereoselectively synthesized in 8-16 steps. One of the three chiral carbons was converted from the chiral center of a yeast-reduction product. The other two chiral carbons were constructed by employing stereoselective allylation and syn-and anti-1,3-reductions. The enantiomeric excesses of the synthesized cryptocarya diacetate and its stereoisomers were determined to be more than 99%ee using a chiral column.

摘要

相似文献

1
Stereoselective syntheses of cryptocarya diacetate and all its stereoisomers in optically pure forms.
Biosci Biotechnol Biochem. 2015;79(1):16-24. doi: 10.1080/09168451.2014.962476. Epub 2014 Sep 25.
2
Enantioselective syntheses of cryptocarya triacetate, cryptocaryolone, and cryptocaryolone diacetate.隐孔木三乙酸酯、隐孔木醇和隐孔木醇二乙酸酯的对映选择性合成。
Org Lett. 2003 May 29;5(11):1959-62. doi: 10.1021/ol0345529.
3
Syntheses of all stereoisomers of goniodiol from yeast-reduction products and their antimicrobiological activity.
Biosci Biotechnol Biochem. 2008 Sep;72(9):2342-52. doi: 10.1271/bbb.80262. Epub 2008 Sep 7.
4
Stereocomplementary synthesis of a natural product-derived compound collection on a solid phase.基于固相的天然产物衍生化合物库的立体互补合成。
Chem Commun (Camb). 2006 Oct 1(37):3868-70. doi: 10.1039/b607816h. Epub 2006 Jul 31.
5
An enantioselective synthesis of cryptocarya diacetate.隐孔木二乙酸酯的对映选择性合成。
Org Lett. 2001 Aug 23;3(17):2777-80. doi: 10.1021/ol016399t.
6
A simple and efficient approach to 1,3-polyols: application to the synthesis of cryptocarya diacetate.一种合成1,3 - 多元醇的简单有效方法：应用于隐孔木二乙酸酯的合成。
Chemistry. 2006 Feb 1;12(5):1397-402. doi: 10.1002/chem.200501029.
7
Total syntheses of (-)- and (+)-boronolide and their plant growth-inhibitory activity.
Biosci Biotechnol Biochem. 2012;76(9):1708-14. doi: 10.1271/bbb.120317. Epub 2012 Sep 7.
8
Efficient asymmetric total syntheses of cryptocarya triacetate, cryptocaryolone, and cryptocaryolone diacetate.隐孔木三乙酸酯、隐孔木醇和隐孔木醇二乙酸酯的高效不对称全合成。
Org Lett. 2009 Jul 16;11(14):3136-8. doi: 10.1021/ol901024t.
9
Syntheses of (-)-cryptocaryolone and (-)-cryptocaryolone diacetate via a diastereoselective oxy-Michael addition and oxocarbenium allylation.通过立体选择性氧迈克尔加成和氧碳正离子烯丙基化反应合成（-）-隐孔菌素和（-）-隐孔菌素二乙酸酯。
J Org Chem. 2012 Aug 17;77(16):6929-36. doi: 10.1021/jo301122b. Epub 2012 Aug 6.
10
Stereochemical assignment of the C1-C6 fragment of psymberin by synthesis and natural product degradation.通过合成和天然产物降解对psymberin的C1-C6片段进行立体化学归属
Org Lett. 2005 Sep 15;7(19):4117-20. doi: 10.1021/ol051396s.