烯丙醇的催化对映选择性溴胺化反应
Catalytic enantioselective bromoamination of allylic alcohols.
作者信息
Qi Juan, Fan Guo-Tao, Chen Jie, Sun Ming-Hui, Dong Yu-Ting, Zhou Ling
机构信息
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China.
出版信息
Chem Commun (Camb). 2014 Nov 18;50(89):13841-4. doi: 10.1039/c4cc05772d.
PMID:25259372
Abstract
An enantioselective bromoamination of allylic alcohols has been developed for the first time using a newly designed cinchona-derived thiourea as the catalyst and N,N-dibromo-4-nitrobenzenesulfonamide as a bromine and amine source.
摘要
首次开发了一种烯丙醇的对映选择性溴胺化反应，使用新设计的金鸡纳衍生硫脲作为催化剂，N,N-二溴-4-硝基苯磺酰胺作为溴和胺源。
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