da Silva G B, Neves R F C, Chiari L, Jones D B, Ali E, Madison D H, Ning C G, Nixon K L, Lopes M C A, Brunger M J
School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide, South Australia 5001, Australia.
Department of Physics, Missouri University of Science and Technology, Rolla, Missouri 65409, USA.
J Chem Phys. 2014 Sep 28;141(12):124307. doi: 10.1063/1.4896072.
We have measured (e,2e) triple differential cross sections (TDCS) for the electron-impact ionisation of phenol with coplanar asymmetrical kinematics for an incident electron energy of 250 eV. Experimental measurements of the angular distribution of the slow outgoing electrons at 20 eV are obtained when the incident electron scatters through angles of -5°, -10°, and -15°, respectively. The TDCS data are compared with calculations performed within the molecular 3-body distorted wave model. In this case, a mixed level of agreement, that was dependent on the kinematical condition being probed, was observed between the theoretical and experimental results in the binary peak region. The experimental intensity of the recoil features under all kinematical conditions was relatively small, but was still largely underestimated by the theoretical calculations.
我们测量了入射电子能量为250 eV时,苯酚在共面不对称运动学条件下电子碰撞电离的(e,2e)三重微分截面(TDCS)。当入射电子分别以-5°、-10°和-15°的角度散射时,获得了20 eV慢出射电子角分布的实验测量结果。将TDCS数据与分子三体畸变波模型内进行的计算进行了比较。在这种情况下,在二元峰区域,理论和实验结果之间观察到了取决于所探测运动学条件的混合程度的一致性。在所有运动学条件下,反冲特征的实验强度相对较小,但理论计算仍大大低估了该强度。