Liu Zhu, Liu Jiannan, Xiao Mengying, Wang Rong, Chen Yeng-Long
Key Laboratory of High Performance Polymer Materials and Technology of Ministry of Education, Department of Polymer Science and Engineering, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University , Nanjing 210093, China.
Institute of Physics , Academia Sinica, Taipei 11529, Taiwan.
Biomicrofluidics. 2014 Sep 10;8(5):054107. doi: 10.1063/1.4893637. eCollection 2014 Sep.
The translocation process of star polymers through a nanochannel is investigated by dissipative particle dynamics simulations. The translocation process is strongly influenced by the star arm arrangement as the polymer enters the channel, and a scaling relation between the translocation time [Formula: see text] and the total number of beads N tot is obtained. Qualitative agreements are found with predictions of the nucleation and growth model for linear block co-polymer translocation. In the intermediate stage where the center of the star polymer is at the channel entrance, the translocation time is found to have power law-dependence on the number of arms outside the channel and very weakly dependent on the number of arms in the channel. Increasing the total number of star arms also increases the star translocation time.
通过耗散粒子动力学模拟研究了星型聚合物通过纳米通道的转位过程。当聚合物进入通道时,转位过程受到星型臂排列的强烈影响,并得到了转位时间[公式:见原文]与总珠子数(N_{tot})之间的标度关系。发现与线性嵌段共聚物转位的成核和生长模型的预测存在定性一致性。在星型聚合物中心位于通道入口的中间阶段,发现转位时间对通道外臂的数量具有幂律依赖性,而对通道内臂的数量依赖性非常弱。增加星型臂的总数也会增加星型聚合物的转位时间。