通过受阻路易斯对实现催化酮加氢。
Enabling catalytic ketone hydrogenation by frustrated Lewis pairs.
机构信息
Department of Chemistry, University of Toronto , 80 St. George Street, Toronto, Ontario M5S 3H6, Canada.
出版信息
J Am Chem Soc. 2014 Nov 12;136(45):15809-12. doi: 10.1021/ja508829x. Epub 2014 Oct 31.
PMID:25333657
Abstract
Hydrogenation of alkyl and aryl ketones using H2 is catalytically achieved in 18 examples using 5 mol % B(C6F5)3 in an ethereal solvent. In these cases the borane and ether behave as a frustrated Lewis pair to activate H2 and effect the reduction.
摘要
使用 H2 催化氢化烷基和芳基酮在 18 个例子中实现，使用 5 mol % 的 B(C6F5)3 在醚溶剂中。在这些情况下，硼烷和醚作为受挫折的路易斯对来激活 H2 并实现还原。
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