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控制用于超级电容器应用的木质素衍生纳米多孔碳的孔隙率。

Controlling porosity in lignin-derived nanoporous carbon for supercapacitor applications.

机构信息

Energy and Environment Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, WA 99354 (USA); Artie McFerrin Department of Chemical Engineering, Texas A&M University, 3122 TAMU, College Station, TX 77843-3122 (USA).

出版信息

ChemSusChem. 2015 Feb;8(3):428-32. doi: 10.1002/cssc.201402621. Epub 2014 Oct 22.

Abstract

Low-cost renewable lignin has been used as a precursor to produce porous carbons. However, to date, it has not been easy to obtain high surface area porous carbon without activation processes or templating agents. Here, we demonstrate that low molecular weight lignin yields highly porous carbon with more graphitization through direct carbonization without additional activation processes or templating agents. We found that molecular weight and oxygen consumption during carbonization are critical factors to obtain high surface area, graphitized porous carbons. This highly porous carbon from low-cost renewable lignin sources is a good candidate for supercapacitor electrode materials.

摘要

低成本可再生木质素已被用作制备多孔碳的前体。然而,迄今为止,如果不采用活化工艺或模板剂,很难获得具有高比表面积的多孔碳。在这里,我们证明了低分子量木质素通过直接碳化而无需额外的活化工艺或模板剂即可生成具有更高石墨化程度的高比表面积多孔碳。我们发现,碳化过程中的分子量和耗氧量是获得高比表面积、石墨化多孔碳的关键因素。这种由低成本可再生木质素资源制备的高多孔碳是超级电容器电极材料的良好候选材料。

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