Comment on "Modeling of electrode polarization for electrolytic cells with a limited ionic adsorption".
作者信息
Alexe-Ionescu A L, Barbero G, Lelidis I
机构信息
University Politehnica of Bucharest, Faculty of Applied Sciences, Splaiul Independentei 313, 060042 Bucharest, Romania and Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy.
Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy and Department of Physics, Solid State Section, University of Athens, Panepistimiopolis, Zografos, Athens 157 84, Greece.
出版信息
Phys Rev E Stat Nonlin Soft Matter Phys. 2014 May;89(5):056401. doi: 10.1103/PhysRevE.89.056401. Epub 2014 May 23.
Recently, Sawada [Phys. Rev. E 88, 032406 (2013)] proposed a model to take into account the dielectric dispersion of ionic origin in a weak electrolyte cell. We first show that the model is based on questionable assumptions. Next, we point out an error in the author's calculation of the current in the external circuit. Finally, we demonstrate why some criticism on recent papers is irrelevant.
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