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丙烯腈-丁二烯-苯乙烯废塑料与废印刷电路板中的非金属颗粒共回收制备再生复合材料。

Co-recycling of acrylonitrile-butadiene-styrene waste plastic and nonmetal particles from waste printed circuit boards to manufacture reproduction composites.

作者信息

Sun Zhixing, Shen Zhigang, Zhang Xiaojing, Ma Shulin

机构信息

a Beijing Key Laboratory for Powder Technology Research and Development , Beijing University of Aeronautics and Astronautics , Beijing 100191 , People's Republic of China.

出版信息

Environ Technol. 2015 Jan-Feb;36(1-4):160-8. doi: 10.1080/09593330.2014.940399. Epub 2014 Jul 28.

Abstract

This study investigated the feasibility of using acrylonitrile-butadiene-styrene (ABS) waste plastic and nonmetal particles from waste printed circuit boards (WPCB) to manufacture reproduction composites (RC), with the aim of co-recycling these two waste resources. The composites were prepared in a twin-crew extruder and investigated by means of mechanical testing, in situ flexural observation, thermogravimatric analysis, and dimensional stability evaluation. The results showed that the presence of nonmetal particles significantly improved the mechanical properties and the physical performance of the RC. A loading of 30 wt% nonmetal particles could achieve a flexural strength of 72.6 MPa, a flexural modulus of 3.57 GPa, and an impact strength of 15.5 kJ/m2. Moreover, it was found that the application of maleic anhydride-grafted ABS as compatilizer could effectively promote the interfacial adhesion between the ABS plastic and the nonmetal particles. This research provides a novel method to reuse waste ABS and WPCB nonmetals for manufacturing high value-added product, which represents a promising way for waste recycling and resolving the environmental problem.

摘要

本研究探讨了利用丙烯腈-丁二烯-苯乙烯(ABS)废塑料和废弃印刷电路板(WPCB)中的非金属颗粒制造再生复合材料(RC)的可行性,目的是对这两种废弃资源进行联合回收利用。复合材料在双螺杆挤出机中制备,并通过力学测试、原位弯曲观察、热重分析和尺寸稳定性评估进行研究。结果表明,非金属颗粒的存在显著改善了再生复合材料的力学性能和物理性能。30 wt%的非金属颗粒负载量可实现72.6 MPa的弯曲强度、3.57 GPa的弯曲模量和15.5 kJ/m²的冲击强度。此外,发现使用马来酸酐接枝ABS作为增容剂可有效促进ABS塑料与非金属颗粒之间的界面粘结。本研究为将废ABS和WPCB非金属用于制造高附加值产品提供了一种新方法,这是一种很有前景的废物回收利用和解决环境问题的途径。

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