氟代硝基亚硝胺，FN(NO2)2 的合成与表征。

Synthesis and characterization of fluorodinitroamine, FN(NO2)2.

机构信息

Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles, CA 90089-1661 (USA).

出版信息

Angew Chem Int Ed Engl. 2015 Jan 19;54(4):1316-20. doi: 10.1002/anie.201410507. Epub 2014 Nov 24.

DOI:10.1002/anie.201410507

Abstract

NF3 and N(NO2)3 are known compounds, whereas the mixed fluoronitroamines, FN(NO2)2 and F2NNO2, have been unknown thus far. One of these, FN(NO2)2, has now been prepared and characterized by multinuclear NMR and Raman spectroscopy. FN(NO2)2 is the first known example of an inorganic fluoronitroamine. It is a thermally unstable, highly energetic material formed by the fluorination of the dinitramide anion using NF4(+) salts as the preferred fluorinating agent.

摘要

NF3 和 N(NO2)3 是已知的化合物，而混合氟硝基胺，FN(NO2)2 和 F2NNO2，迄今尚未被发现。其中之一，FN(NO2)2，现已通过多核 NMR 和拉曼光谱法进行了制备和表征。FN(NO2)2 是首例已知的无机氟硝基胺。它是一种热不稳定的高能材料，由使用 NF4(+)盐作为首选氟化剂对二硝酰胺阴离子进行氟化而形成。