[(NHC)MX(cod)]和[(NHC)MCl(CO)₂]（M = Rh，Ir；X = Cl，I）配合物的简便合成
Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO)2] (M = Rh, Ir; X = Cl, I) complexes.
作者信息
Savka R, Plenio H
机构信息
Organometallic Chemistry, Alarich-Weiss-Str. 12, Fachbereich Chemie, TU Darmstadt, 64287 Darmstadt, Germany.
出版信息
Dalton Trans. 2015 Jan 21;44(3):891-3. doi: 10.1039/c4dt03449j.
PMID:25437103
Abstract
The reactions of [MCl(cod)]2 (M = Rh, Ir) with different NHC·HX (X = Cl, I), K2CO3 in technical grade acetone under air provide simple access to various [(NHC)MX(cod)] complexes; a facile one-pot synthesis of [(NHC)MCl(CO)2] (M = Rh, Ir) is also reported.
摘要
[MCl(cod)]2（M = Rh，Ir）与不同的NHC·HX（X = Cl，I）、碳酸钾在工业级丙酮中于空气中反应，可简便地制备各种[(NHC)MX(cod)]配合物；还报道了[(NHC)MCl(CO)2]（M = Rh，Ir）的简便一锅法合成。
Zotero 插件