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用于高性能钠离子电池阳极的碳纳米管上具有扩展(002)面间距的超薄MoS₂纳米片的生长

Growth of ultrathin MoS₂ nanosheets with expanded spacing of (002) plane on carbon nanotubes for high-performance sodium-ion battery anodes.

作者信息

Zhang Shen, Yu Xianbo, Yu Hailong, Chen Yujin, Gao Peng, Li Chunyan, Zhu Chunling

机构信息

Key Laboratory of In-Fiber Integrated Optics, Ministry of Education, and College of Science, and ‡College of Material Science and Chemical Engineering, Harbin Engineering University , Harbin, China.

出版信息

ACS Appl Mater Interfaces. 2014 Dec 24;6(24):21880-5. doi: 10.1021/am5061036. Epub 2014 Dec 8.

Abstract

A hydrothermal method was developed to grow ultrathin MoS2 nanosheets, with an expanded spacing of the (002) planes, on carbon nanotubes. When used as a sodium-ion battery anode, the composite exhibited a specific capacity of 495.9 mAh g(-1), and 84.8% of the initial capacity was retained after 80 cycles, even at a current density of 200 mA g(-1). X-ray diffraction analyses show that the sodiation/desodiation mechanismis based on a conversion reaction. The high capacity and long-term stability at a high current ate demonstrate that the composite is a very promising candidate for use as an anode material in sodium-ion batteries.

摘要

开发了一种水热法,用于在碳纳米管上生长具有扩展的(002)面间距的超薄MoS2纳米片。当用作钠离子电池阳极时,该复合材料的比容量为495.9 mAh g(-1),即使在200 mA g(-1)的电流密度下,80次循环后仍保留了初始容量的84.8%。X射线衍射分析表明,钠化/脱钠机制基于转化反应。在高电流密度下的高容量和长期稳定性表明,该复合材料是用作钠离子电池阳极材料的非常有前途的候选材料。

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