Crystal structure of 1,1'-bis[1,7-dicarba-closo-dodeca-borane(11)].
作者信息
Elrick Lisa, Rosair Georgina M, Welch Alan J
机构信息
Institute of Chemical Sciences, School of Engineering & Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, Scotland.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Oct 24;70(Pt 11):376-8. doi: 10.1107/S1600536814022132. eCollection 2014 Nov 1.
Abstract
In the title compound, C4H22B20, the two {1,7-closo-C2B10H11} cages are linked across a centre of inversion, with C-C = 1.5401 (16) Å. The position of the second non-linking cage C atom was established unambiguously by geometric and crystallographic methods and there is no evidence of C/B disorder.
摘要
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本文引用的文献
1
The Cambridge Structural Database in retrospect and prospect.
Angew Chem Int Ed Engl. 2014 Jan 13;53(3):662-71. doi: 10.1002/anie.201306438. Epub 2014 Jan 2.
2
Asymmetric 1,8/13,2,x-M2C2B10 14-vertex metallacarboranes by direct electrophilic insertion reactions; the VCD and BHD methods in critical analysis of cage C atom positions.
Dalton Trans. 2014 Apr 7;43(13):5095-105. doi: 10.1039/c3dt52101j.
3
The VCD method--a simple and reliable way to distinguish cage C and B atoms in (hetero)carborane structures determined crystallographically.
Dalton Trans. 2013 Jan 21;42(3):645-64. doi: 10.1039/c2dt31515g.
4
The first supraicosahedral bis(heteroborane).
Chem Commun (Camb). 2010 Oct 21;46(39):7394-6. doi: 10.1039/c0cc02534h. Epub 2010 Sep 7.
5
Room-temperature C-C bond cleavage of an arene by a metallacarborane.
Angew Chem Int Ed Engl. 2010 Jul 5;49(29):4943-5. doi: 10.1002/anie.201001555.
6
A short history of SHELX.
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
7
Structural Characterization of Representative d(7), d(8), and d(9) Transition Metal Complexes of Bis(o-carborane).
Inorg Chem. 1997 Dec 3;36(25):5951-5955. doi: 10.1021/ic9706313.
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