Xu Xi-Bin, Luo Jiang-Shan, Liu Miao, Wang Yu-Ying, Yi Zao, Li Xi-Bo, Yi You-Gen, Tang Yong-Jian
College of Physics and Electronics, Central South University, Changsha 410083, China.
Phys Chem Chem Phys. 2015 Jan 28;17(4):2641-50. doi: 10.1039/c4cp04714a. Epub 2014 Dec 11.
In this paper a simulation of the properties of surface plasmons on gold nanoplatelets with various cross-sections inscribed in a circle and an investigation of their field distributions to assign multiple SPRs are described. The manipulated propagation can be obtained through the evolution of edges and corners. Furthermore, the particle morphology and the associated spectral positions alone do not uniquely reflect the important details of the local field distribution or the resonance modes. The plasmon modes were investigated and found to be mainly excited along the edges and in the side and sloped side surfaces. The strong field distributions can generally be found around the corners and how the plasmons transmit through the corners to adjacent edges was also investigated. Besides the plasmons excited along the edges as were found for the triangular nanoplatelets, plasmons were excited in the interior region of the triangular surfaces and were also investigated. Despite this in the infrared region, plasmon modes were found to be along the edges for the hexagonal nanoplatelets. Also, it can be seen that the change of nanoplatelet thickness can support different plasmon modes ranging from dipolar resonance mode to quadrupole resonance mode. The thickness far below the skin depth can display complex plasmon modes along the edges and on the side and sloping side surfaces as well as the strong coupling between the top and bottom surfaces. The observed plasmon resonance modes in this simulation reflect the interference of all these contributions including the plasmons along the edges and on the side surfaces. This is an essential step towards a thorough understanding of plasmon modes and the effect of edge and corner evolution in polygonous nanoplatelets.
本文描述了对刻在圆内具有各种横截面的金纳米片表面等离激元性质的模拟,以及对其场分布的研究以确定多个表面等离激元共振(SPR)。通过边缘和角落的演变可以实现对传播的操控。此外,仅粒子形态和相关的光谱位置并不能唯一地反映局部场分布或共振模式的重要细节。对等离激元模式进行了研究,发现其主要沿边缘以及侧面和倾斜侧面被激发。通常可以在角落周围发现强场分布,并且还研究了等离激元如何通过角落传输到相邻边缘。除了在三角形纳米片中发现的沿边缘激发的等离激元外,还对三角形表面内部区域激发的等离激元进行了研究。尽管如此,在红外区域,发现六边形纳米片的等离激元模式沿边缘分布。此外,可以看出纳米片厚度的变化能够支持从偶极共振模式到四极共振模式的不同等离激元模式。远低于趋肤深度的厚度可以在边缘以及侧面和倾斜侧面展示复杂的等离激元模式,以及顶面和底面之间的强耦合。在该模拟中观察到的等离激元共振模式反映了所有这些贡献的干涉,包括沿边缘和侧面的等离激元。这是朝着全面理解等离激元模式以及多边形纳米片中边缘和角落演变的影响迈出的重要一步。