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一种基于(7,8)连接的双Wells-Dawson簇的前所未有的三维有机金属有机框架:合成、结构、电催化和光催化性能。

An unprecedented 3D POM-MOF based on (7,8)-connected twin Wells-Dawson clusters: synthesis, structure, electrocatalytic and photocatalytic properties.

作者信息

Li Shaobin, Zhang Li, O'Halloran Kevin P, Ma Huiyuan, Pang Haijun

机构信息

Key Laboratory of Green Chemical Engineering and Technology of College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040, China.

出版信息

Dalton Trans. 2015 Feb 7;44(5):2062-5. doi: 10.1039/c4dt03625e.

Abstract

The first (7,8)-connected polyoxometalate-based metal-organic framework (POM-MOF) has been constructed from seven- and eight-connected twin Wells-Dawson clusters, and possesses the highest connection number of polyoxometalates to any mixed-connected POM-MOF to date and a unique structural motif that contains both organic-inorganic and all-inorganic networks.

摘要

首个基于(7,8)连接的多金属氧酸盐的金属有机框架(POM-MOF)由七连接和八连接的双Wells-Dawson簇构建而成,拥有多金属氧酸盐与迄今所有混合连接的POM-MOF相比最高的连接数,以及一个同时包含有机-无机和全无机网络的独特结构基序。

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