树枝状分子在帕塞里尼三组分反应中的反应活性增强。
Enhanced reactivity of dendrons in the Passerini three-component reaction.
作者信息
Jee Jo-Ann, Song Shuang, Rudick Jonathan G
机构信息
Department of Chemistry, Stony Brook University, Stony Brook, NY 11794, USA.
出版信息
Chem Commun (Camb). 2015 Mar 28;51(25):5456-9. doi: 10.1039/c4cc10091c.
PMID:25584705
Abstract
Polymer chemistry has embraced multicomponent reactions for synthesizing multifunctional materials, including structurally perfect multimodal dendrimers. An unexpected substituent effect dramatically shortens the time required for the convergent synthesis of dendrimers via the Passerini three-component reaction.
摘要
高分子化学已采用多组分反应来合成多功能材料，包括结构完美的多模态树枝状大分子。一种意想不到的取代基效应显著缩短了通过帕塞里尼三组分反应进行树枝状大分子收敛合成所需的时间。
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