Sagade Abhay A, Neumaier Daniel, Schall Daniel, Otto Martin, Pesquera Amaia, Centeno Alba, Elorza Amaia Zurutuza, Kurz Heinrich
Advanced Microelectronic Center Aachen (AMICA), AMO GmbH, Otto-Blumenthal-Strasse 25, 52074, Aachen, Germany.
Nanoscale. 2015 Feb 28;7(8):3558-64. doi: 10.1039/c4nr07457b.
The sensitivity of graphene based devices to surface adsorbates and charge traps at the graphene/dielectric interface requires proper device passivation in order to operate them reproducibly under ambient conditions. Here we report on the use of atomic layer deposited aluminum oxide as passivation layer on graphene field effect devices (GFETs). We show that successful passivation produce hysteresis free DC characteristics, low doping level GFETs stable over weeks though operated and stored in ambient atmosphere. This is achieved by selecting proper seed layer prior to deposition of encapsulation layer. The passivated devices are also demonstrated to be robust towards the exposure to chemicals and heat treatments, typically used during device fabrication. Additionally, the passivation of high stability and reproducible characteristics is also shown for functional devices like integrated graphene based inverters.
基于石墨烯的器件对石墨烯/电介质界面处的表面吸附物和电荷陷阱很敏感,为了在环境条件下可重复地操作它们,需要对器件进行适当的钝化处理。在此,我们报道了在石墨烯场效应晶体管(GFET)上使用原子层沉积氧化铝作为钝化层。我们表明,成功的钝化产生无滞后的直流特性,低掺杂水平的GFET在环境大气中操作和存储数周仍保持稳定。这是通过在沉积封装层之前选择合适的种子层来实现的。钝化后的器件还被证明对器件制造过程中常用的化学暴露和热处理具有鲁棒性。此外,对于基于集成石墨烯的逆变器等功能器件,也展示了具有高稳定性和可重复性特征的钝化效果。