人工合成的锰（IV）钙氧化物配合物模拟了光系统II中的析氧复合物。
Artificial synthetic Mn(IV)Ca-oxido complexes mimic the oxygen-evolving complex in photosystem II.
作者信息
Chen Changhui, Zhang Chunxi, Dong Hongxing, Zhao Jingquan
机构信息
Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
出版信息
Dalton Trans. 2015 Mar 14;44(10):4431-5. doi: 10.1039/c4dt03459g.
PMID:25662151
Abstract
A novel family of heteronuclear Mn(IV)Ca-oxido complexes containing Mn(IV)Ca-oxido cuboidal moieties and reactive water molecules on Ca(2+) have been synthesized and characterized to mimic the oxygen-evolving complex (OEC) of photosystem II (PSII) in nature.
摘要
已合成并表征了一类新型的异核锰（IV）钙-氧化物配合物，其包含锰（IV）钙-氧化物立方块部分以及钙（2+）上的活性水分子，用于模拟自然界中光系统II（PSII）的析氧复合物（OEC）。
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