配位驱动的角棱柱状笼的自组装及大笼腔中三个杂 guests 的包合。
Coordination-driven self-assembly of an iridium-cornered prismatic cage and encapsulation of three heteroguests in its large cavity.
机构信息
Department of Chemistry, University of Ulsan, Ulsan 680-749, Republic of Korea.
出版信息
Chem Commun (Camb). 2015 Mar 14;51(21):4492-5. doi: 10.1039/c4cc09494h.
PMID:25682749
Abstract
A hollow iridium-cornered prismatic cage was self-assembled without the assistance of any template. The cage was found to be capable of encapsulating heteroguest's triplet in its perfect sized cavity, producing the first demonstration of quintuple structure by an octahedral metal cornered prismatic cage.
摘要
一个无模板辅助的自组装的中空的角隅为铱的正八面体棱柱笼被发现能够将三重态的客体分子封装在其完美尺寸的空腔内，这是首例通过八面体金属角隅棱柱笼来实现五重结构的例证。
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