使用铝胺 - 酚盐配合物进行环氧环己烷的开环聚合反应。
Ring-opening polymerization of cyclohexene oxide using aluminum amine-phenolate complexes.
作者信息
Plommer Hart, Reim Immanuel, Kerton Francesca M
机构信息
Department of Chemistry, Memorial University of Newfoundland, St. John's, NL A1B 3X7, Canada.
出版信息
Dalton Trans. 2015 Jul 21;44(27):12098-102. doi: 10.1039/c5dt00220f.
PMID:25688548
Abstract
Remarkably active (down to 0.001% Al) catalysts for ring-opening polymerization of cyclohexene oxide under neat reaction conditions are reported. High molecular weight polymers with uniform dispersity are produced. Kinetic data from NMR studies and MALDI-TOF MS data of the polymers provide some mechanistic insight.
摘要
据报道，在纯反应条件下，用于环氧环己烷开环聚合的催化剂具有显著活性（低至0.001%的铝）。可制备出具有均匀分散性的高分子量聚合物。聚合物的核磁共振研究动力学数据和基质辅助激光解吸电离飞行时间质谱数据提供了一些机理见解。
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