Atkinson Colin, Martineau Philip M, Khan Rizwan U A, Field John E, Fisher David, Davies Nick M, Samartseva Julia V, Putterman Seth J, Hird Jonathan R
Department of Mathematics, Imperial College London, London, UK Schlumberger Gould Research, Cambridge, UK.
DTC Research Centre, Maidenhead, Berkshire, UK.
Philos Trans A Math Phys Eng Sci. 2015 Mar 28;373(2038). doi: 10.1098/rsta.2014.0270.
The degree of surface roughness and clarity with which a surface in a brittle material can be formed via fracture is known to be related to the speed of the propagating crack. Cracks traversing a brittle material at low speed produce very smooth surfaces, while those propagating faster create less reflective and rough surfaces (Buehler MJ, Gao H. 2006 Nature 439, 307-310 (doi:10.1038/nature04408)). The elastic wave speeds (c(l)≈18 000 m s(-1), c(s)≈11 750 m s(-1)) in diamond are fast (Willmott GR, Field JE. 2006 Phil. Mag. 86, 4305-4318 (doi:10.1080/14786430500482336)) and present a particular problem in creating smooth surfaces during the cleaving of diamond-a routine operation in the fashioning of diamonds for gemstone purposes--as the waves are reflected from the boundaries of the material and can add a tensile component to the propagating crack tip causing the well-known cleavage steps observed on diamond surfaces (Field JE. 1971 Contemp. Phys. 12, 1-31 (doi:10.1080/00107517108205103); Field JE. 1979 Properties of diamond, 1st edn, Academic Press; Wilks EM. 1958 Phil. Mag. 3, 1074-1080 (doi:10.1080/14786435808237036)). Here we report an analysis of two diamonds, having large dimensions and high aspect ratio, which from a gemological analysis are shown to have been cleaved from the same 200 carat specimen. A methodology for their manufacture is calculated by an analysis of a model problem. This takes into account the effect of multiple reflections from the sample boundaries. It is suggested that the lapidary had an intuitive guide to how to apply the cleavage force in order to control the crack speed. In particular, it is shown that it is likely that this technique caused the fracture to propagate at a lower speed. The sacrifice of a large diamond with the intention of creating thin plates, rather than a faceted gemstone, demonstrates how symbolism and beliefs associated with gemstones have changed over the centuries (Harlow GE. 1998 The nature of diamonds, Cambridge University Press). The scientific insights gained by studying these gemstones suggest a method of producing macroscale atomically flat and stress-free surfaces on other brittle materials.
脆性材料中的表面通过断裂形成时的表面粗糙度和清晰度程度,已知与扩展裂纹的速度有关。低速穿过脆性材料的裂纹会产生非常光滑的表面,而那些传播速度较快的裂纹会产生反射性较差且粗糙的表面(布勒·M·J,高·H。2006年《自然》439卷,307 - 310页(doi:10.1038/nature04408))。钻石中的弹性波速度(纵波速度c(l)≈18000米/秒,横波速度c(s)≈11750米/秒)很快(威尔莫特·G·R,菲尔德·J·E。2006年《哲学杂志》86卷,4305 - 4318页(doi:10.1080/14786430500482336)),这在为宝石用途切割钻石(这是钻石加工中的常规操作)过程中,在创建光滑表面时带来了特殊问题,因为波会从材料边界反射,并且会给扩展裂纹尖端增加拉伸分量,从而导致在钻石表面观察到众所周知的解理台阶(菲尔德·J·E。1971年《当代物理学》12卷,1 - 31页(doi:10.1080/00107517108205103);菲尔德·J·E。1979年《钻石的性质》,第1版,学术出版社;威尔克斯·E·M。1958年《哲学杂志》3卷,1074 - 1080页(doi:10.1080/14786435808237036))。在此,我们报告对两颗尺寸大且长宽比高的钻石的分析,从宝石学分析来看,它们是从同一个200克拉的标本上切割下来的。通过对一个模型问题的分析计算出了它们的制造方法。这考虑了来自样品边界的多次反射的影响。有人认为宝石匠对于如何施加解理力以控制裂纹速度有一种直观的指导。特别是,结果表明很可能这种技术使断裂以较低速度传播。为了制造薄板而牺牲一颗大钻石,而不是制作有刻面的宝石,这表明了几个世纪以来与宝石相关的象征意义和信仰是如何变化的(哈洛·G·E。1998年《钻石的本质》,剑桥大学出版社)。通过研究这些宝石获得的科学见解提出了一种在其他脆性材料上制造宏观尺度原子级平整且无应力表面的方法。