Li Jingsong, Yu Benli, Fischer Horst
Key Laboratory of Opto-Electronic Information Acquisition and Manipulation of Ministry of Education, Anhui University, No. 111 Jiulong Road, Hefei 230039, China.
Appl Spectrosc. 2015 Apr;69(4):496-506. doi: 10.1366/14-07629. Epub 2015 Mar 1.
This paper presents a novel methodology-based discrete wavelet transform (DWT) and the choice of the optimal wavelet pairs to adaptively process tunable diode laser absorption spectroscopy (TDLAS) spectra for quantitative analysis, such as molecular spectroscopy and trace gas detection. The proposed methodology aims to construct an optimal calibration model for a TDLAS spectrum, regardless of its background structural characteristics, thus facilitating the application of TDLAS as a powerful tool for analytical chemistry. The performance of the proposed method is verified using analysis of both synthetic and observed signals, characterized with different noise levels and baseline drift. In terms of fitting precision and signal-to-noise ratio, both have been improved significantly using the proposed method.
本文提出了一种基于离散小波变换(DWT)的新颖方法以及最优小波对的选择,以自适应处理可调谐二极管激光吸收光谱(TDLAS)光谱用于定量分析,如分子光谱和痕量气体检测。所提出的方法旨在构建一个适用于TDLAS光谱的最优校准模型,而不考虑其背景结构特征,从而促进TDLAS作为分析化学的强大工具的应用。使用具有不同噪声水平和基线漂移的合成信号和观测信号分析验证了所提方法的性能。在所提方法下,拟合精度和信噪比均得到了显著提高。