Ward Jeremy W, Lamport Zachary A, Jurchescu Oana D
Department of Physics, Wake Forest University, 1834 Wake Forest Rd, Winston-Salem, NC 27109 (USA).
Chemphyschem. 2015 Apr 27;16(6):1118-32. doi: 10.1002/cphc.201402757. Epub 2015 Mar 10.
A selection of the latest developments in organic electronic materials and organic field-effect transistor (OFET) devices is reviewed here with an emphasis on the synthetic and manufacturing versatility, ease of processing, and low cost offered by solution processability. At the heart of these benefits is the nature of the weak van der Waals intermolecular interactions inherent to organic compounds. This allows processability with a relatively small amount of energy investment. Material solubility, in particular, creates unique pathways for film fabrication and the design of new device architectures, while presenting new manufacturing challenges to explore. In this review we provide a chronological presentation of the important developments in the solution-deposited organic small-molecule semiconductor, dielectric, and electrode materials used in OFETs, making specific note of current benchmarks. Organic device architectures and fabrication methods that are characterized by reduced complexity and ease of implementation are discussed.
本文综述了有机电子材料和有机场效应晶体管(OFET)器件的一些最新进展,重点关注溶液可加工性所带来的合成和制造多功能性、易于加工以及低成本。这些优势的核心在于有机化合物固有的弱范德华分子间相互作用的性质。这使得在能量投入相对较少的情况下即可进行加工。特别是材料的溶解性为薄膜制造和新器件架构的设计创造了独特途径,同时也带来了有待探索的新制造挑战。在本综述中,我们按时间顺序介绍了用于OFET的溶液沉积有机小分子半导体、电介质和电极材料的重要进展,并特别指出了当前的基准。还讨论了具有降低复杂性和易于实施特点的有机器件架构和制造方法。