二配位氢化锗烯
Two-coordinate hydrido-germylenes.
作者信息
Hadlington Terrance J, Schwarze Benedikt, Izgorodina Ekaterina I, Jones Cameron
机构信息
School of Chemistry, Monash University, P.O. Box 23, Melbourne, VIC 3800, Australia.
出版信息
Chem Commun (Camb). 2015 Apr 21;51(31):6854-7. doi: 10.1039/c5cc01314c.
PMID:25791698
Abstract
The first structurally characterised two-coordinate hydrido-germylenes, :Ge(H)L (L = -N(Ar){Si(OBu)}, Ar = C6H2{C(H)Ph2}2R-2,6,4; R = Pr(i) ((tBuO)L(†)), Me ((tBuO)L*)), have been prepared, and their dimerisation shown to be thermodynamically unfavourable, largely due to the extreme steric bulk of their amide ligands.
摘要
首个结构已明确的双配位氢化亚锗烯，:Ge(H)L（L = -N(Ar){Si(OBu)}，Ar = C6H2{C(H)Ph2}2R-2,6,4；R = Pr(i)（(tBuO)L(†)），Me（(tBuO)L*））已被制备出来，并且其偶联反应在热力学上是不利的，这主要归因于其酰胺配体的极度空间位阻。
Zotero 插件