非血红素铁（II）配合物对苯丙酮酸的双氧活化及连续两次氧化脱羧反应：羟基扁桃酸合酶（HMS）和CloR的功能模型
Dioxygen activation and two consecutive oxidative decarboxylations of phenylpyruvate by nonheme iron(II) complexes: functional models of hydroxymandelate synthase (HMS) and CloR.
作者信息
Sheet Debobrata, Bhattacharya Shrabanti, Paine Tapan Kanti
机构信息
Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 2A&2B Raja S. C. Mullick Road, Jadavpur, Kolkata-700032, India.
出版信息
Chem Commun (Camb). 2015 May 4;51(36):7681-4. doi: 10.1039/c5cc01652e.
PMID:25850011
Abstract
Two mononuclear iron(ii)-phenylpyruvate complexes of monoanionic facial N3 ligands are reported to react with dioxygen to undergo two consecutive oxidative decarboxylation steps via an iron-mandelate complex mimicking the function of HMS and CloR.
摘要
据报道，两种单核铁（II）-苯基丙酮酸与单阴离子面式N3配体的配合物与氧气反应，通过模拟HMS和CloR功能的铁-扁桃酸配合物经历两个连续的氧化脱羧步骤。
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