氟化醇作为将二氧化碳无溶剂化学固定为环氧化物的活化剂。
Fluorinated Alcohols as Activators for the Solvent-Free Chemical Fixation of Carbon Dioxide into Epoxides.
作者信息
Gennen Sandro, Alves Margot, Méreau Raphaël, Tassaing Thierry, Gilbert Bernard, Detrembleur Christophe, Jerome Christine, Grignard Bruno
机构信息
Center for Education and Research on Macromolecules (CERM), Chemistry Department, B6a, University of Liège allée du 6 août, 4000 Liege (Belgium).
Institut des Sciences Moléculaires (ISM), UMR5255 CNRS, Université de Bordeaux, 351 Cours de la libération, 33405 Talence Cedex (France).
出版信息
ChemSusChem. 2015 Jun 8;8(11):1845-9. doi: 10.1002/cssc.201500103. Epub 2015 May 7.
The addition of fluorinated alcohols to onium salts provides highly efficient organocatalysts for the chemical fixation of CO2 into epoxides under mild experimental conditions. The combination of online kinetic studies, NMR titrations and DFT calculations allows understanding this synergistic effect that provides an active organocatalyst for CO2 /epoxides coupling.
在鎓盐中加入氟化醇可提供高效的有机催化剂，用于在温和的实验条件下将二氧化碳化学固定为环氧化物。在线动力学研究、核磁共振滴定和密度泛函理论计算相结合，有助于理解这种协同效应，该效应为二氧化碳/环氧化物偶联提供了一种活性有机催化剂。
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