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通过两步阳极氧化工艺形成纳米多孔结构来测定铝合金抗气蚀特性的硫酸浓度

Determination of sulfuric acid concentration for anti-cavitation characteristics of Al alloy by two step anodizing process to forming nano porous.

作者信息

Lee Seung-Jun, Kim Seong-Kweon, Jeong Jae-Yong, Kim Seong-Jong

出版信息

J Nanosci Nanotechnol. 2014 Dec;14(12):9572-8. doi: 10.1166/jnn.2014.10179.

Abstract

Al alloy is a highly active metal but forms a protective oxide film having high corrosion resistance in atmosphere environment. However, the oxide film is not suitable for practical use, since the thickness of the film is not uniform and it is severly altered with formation conditions. This study focused on developing an aluminum anodizing layer having hardness, corrosion resistance and abrasion resistance equivalent to a commercial grade protective layer. Aluminum anodizing layer was produced by two-step aluminum anodizing oxide (AAO) process with different sulfuric acid concentrations, and the cavitation characteristics of the anodized coating layer was investigated. In hardness measurement, the anodized coating layer produced with 15 vol.% of sulfuric acid condition had the highest value of hardness but exhibited poor cavitation resistance due to being more brittle than those with other conditions. The 10 vol.% of sulfuric acid condition was thus considered to be the optimum condition as it had the lowest weight loss and damage depth.

摘要

铝合金是一种活性很高的金属,但在大气环境中会形成具有高耐腐蚀性的保护性氧化膜。然而,该氧化膜不适合实际应用,因为膜的厚度不均匀,且会随形成条件而严重变化。本研究的重点是开发一种硬度、耐腐蚀性和耐磨性与商业级保护层相当的铝阳极氧化层。通过两步铝阳极氧化氧化物(AAO)工艺,在不同硫酸浓度下制备了铝阳极氧化层,并研究了阳极氧化涂层的空蚀特性。在硬度测量中,在15体积%硫酸条件下制备的阳极氧化涂层硬度值最高,但由于比其他条件下的涂层更脆,其耐空蚀性较差。因此,10体积%硫酸条件被认为是最佳条件,因为它的重量损失和损伤深度最低。

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