Liu Xiaona, Lu Qifang, Wei Mingzhi, Wang Cuiqing, Liu Suwen
School of Material Science and Engineering, Qilu University of Technology, Jinan, 250353, P. R. China.
Lunan Research Institute of Coal Chemistry, Jining, 272000, P. R. China.
Chem Asian J. 2015 Aug;10(8):1710-6. doi: 10.1002/asia.201500262. Epub 2015 Jun 16.
One-dimensional (1D) CeO2 /Bi2 WO6 heterostructured nanofibers with a diameter of about 300 nm were successfully synthesized by using a straightforward strategy combining an electrospinning technique with a sintering process. The acquired products were characterized by thermogravimetric and differential scanning calorimetric (TG-DSC), Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) surface area measurements, and UV/Vis spectroscopy. The obtained CeO2 /Bi2 WO6 heterostructured nanofibers exhibited an excellent photocatalytic property for the degradation of Rhodamine B (RhB) dye driven by visible light due to the promoted separation of photoelectrons and holes and the large contact area between the photocatalyst and organic pollutant.
采用静电纺丝技术与烧结工艺相结合的简单策略,成功合成了直径约300 nm的一维(1D)CeO2 /Bi2 WO6异质结构纳米纤维。通过热重和差示扫描量热法(TG-DSC)、傅里叶变换红外(FT-IR)光谱、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)、X射线光电子能谱(XPS)、布鲁诺尔-埃米特-泰勒(BET)表面积测量以及紫外/可见光谱对所得产物进行了表征。由于光电子和空穴的分离得到促进以及光催化剂与有机污染物之间的大接触面积,所制备的CeO2 /Bi2 WO6异质结构纳米纤维在可见光驱动下对罗丹明B(RhB)染料的降解表现出优异的光催化性能。