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基于西兰花形状的 TiO2 纳米棒组装的天然染料敏化太阳能电池。

Natural dye sensitized TiO2 nanorods assembly of broccoli shape based solar cells.

机构信息

Department of Physics, Coimbatore Institute of Technology, Coimbatore, Tamil Nadu, India.

Department of Engineering, University College of Bergen, Bergen, Norway.

出版信息

J Photochem Photobiol B. 2015 Jul;148:223-231. doi: 10.1016/j.jphotobiol.2015.04.017. Epub 2015 May 1.

Abstract

TiO2 nanorods based thin films with rutile phase have been synthesized using template free low temperature hydrothermal method. The scanning electron microscope images showed that the prepared TiO2 samples were made of TiO2 nanorods and the nanorods had arranged by itself to form a broccoli like shape. The X-ray diffraction studies revealed that the prepared TiO2 samples exhibit rutile phase. The grown TiO2 nanorods had been sensitized using the flowers of Sesbania (S) grandiflora, leaves of Camellia (C) sinensis and roots of Rubia (R) tinctorum. Dye sensitized solar cells had been fabricated using the natural dye sensitized TiO2 nanorods based thin film photoelectrode and the open circuit voltage and short circuit current density were found to lie in the range of 0.45-0.6 V and 5.6-6.4 mA/cm(2) respectively. The photovoltaic performance of all the fabricated natural dye sensitized TiO2 solar cells indicate that natural dyes have the potential to be used as effective sensitizer in dye sensitized solar cells.

摘要

采用无模板低温水热法合成了具有金红石相的 TiO2 纳米棒薄膜。扫描电子显微镜图像显示,所制备的 TiO2 样品由 TiO2 纳米棒组成,纳米棒自行排列形成类似西兰花的形状。X 射线衍射研究表明,所制备的 TiO2 样品呈现金红石相。采用田菁(S)grandiflora 的花、茶树(C)sinensis 的叶和茜草根(R)tinctorum 对生长的 TiO2 纳米棒进行敏化。使用天然染料敏化的 TiO2 纳米棒薄膜光电极制备了染料敏化太阳能电池,开路电压和短路电流密度分别在 0.45-0.6 V 和 5.6-6.4 mA/cm(2)的范围内。所有制备的天然染料敏化 TiO2 太阳能电池的光伏性能表明,天然染料具有作为染料敏化太阳能电池中有效敏化剂的潜力。

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