Michez Lisa, Chen Kai, Cheynis Fabien, Leroy Frédéric, Ranguis Alain, Jamgotchian Haik, Hanbücken Margrit, Masson Laurence
Aix Marseille Université, CNRS, CINaM UMR 7325, 13288 Marseille, France.
Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin - BP 48, 91192 Gif-sur-Yvette Cedex, France.
Beilstein J Nanotechnol. 2015 Mar 19;6:777-84. doi: 10.3762/bjnano.6.80. eCollection 2015.
We demonstrate the kinetically controlled growth of one-dimensional Co nanomagnets with a high lateral order on a nanopatterned Ag(110) surface. First, self-organized Si nanoribbons are formed upon submonolayer condensation of Si on the anisotropic Ag(110) surface. Depending on the growth temperature, individual or regular arrays (with a pitch of 2 nm) of Si nanoribbons can be grown. Next, the Si/Ag(110) system is used as a novel one-dimensional Si template to guide the growth of Co dimer nanolines on top of the Si nanoribbons, taking advantage of the fact that the thermally activated process of Co diffusion into the Si layer is efficiently hindered at 220 K. Magnetic characterization of the Co nanolines using X-ray magnetic circular dichroism reveals that the first atomic Co layer directly adsorbed onto the Si nanoribbons presents a weak magnetic response. However, the second Co layer exhibits an enhanced magnetization, strongly suggesting a ferromagnetic ordering with an in-plane easy axis of magnetization, which is perpendicular to the Co nanolines.
我们展示了在纳米图案化的Ag(110)表面上动力学控制生长具有高横向有序性的一维钴纳米磁体。首先,在各向异性的Ag(110)表面上亚单层硅凝聚时形成自组织的硅纳米带。根据生长温度,可以生长出单个的或规则阵列(间距为2纳米)的硅纳米带。接下来,利用在220 K时钴扩散到硅层的热激活过程受到有效阻碍这一事实,将Si/Ag(110)体系用作一种新型的一维硅模板,以引导钴二聚体纳米线在硅纳米带顶部生长。使用X射线磁性圆二色性对钴纳米线进行磁性表征表明,直接吸附在硅纳米带上的第一层钴原子呈现出微弱的磁响应。然而,第二层钴表现出增强的磁化强度,强烈表明存在具有面内易磁化轴的铁磁有序,该易磁化轴垂直于钴纳米线。