Gao Guang-zhen, Cai Ting-dong, Hu Bo, Jia Tian-jun
Guang Pu Xue Yu Guang Pu Fen Xi. 2015 Jan;35(1):34-7.
Tunable diode laser absorption spectroscopy (TDLAS) is a widely used technique for high sensitivity, good selectivity and fast response. It is widely used in environment monitoring, industrial process control and biomedical sensing. In order to overcome the drawbacks of TDLAS including high cost, poor stability and center wavelength shift problem. A multi-mode diode laser system based on correlation spectroscopy and wavelength modulation spectroscopy (TMDL-COSPEC-WMS) was used to measure O2 concentration near 760nm at the 1%~30% range of near room temperature. During the experiment, the light is splitter into two beams, respectively through the sample and measuring cell, two receiving optical signal collection containing gas concentration information sent back stage treatment, invert the oxygen concentration through correlation and ratio between measured signal and reference signal, the correlation spectroscopy harmonic detection technique is used to improve the stability of the system and the signal to noise ratio. The result showed that, there was a good linear relationship between the measured oxygen concentration and the actual concentration value. A detection limit of 280 pmm. m in the 1 atmospheric which approved of the same sample. A continuous measurement for oxygen with the standard deviation of 0. 056% in ambient air during approximately 30 minutes confirms the stability and the capability of the system. The design of the system includes soft and hardware can meet the needs of oxygen online monitoring. The experimental device is simple and easy to use, easy to complex environment application.
可调谐二极管激光吸收光谱技术(TDLAS)是一种广泛应用的技术,具有高灵敏度、良好的选择性和快速响应特性。它在环境监测、工业过程控制和生物医学传感等领域有着广泛应用。为了克服TDLAS存在的高成本、稳定性差以及中心波长漂移等缺点。采用了一种基于相关光谱和波长调制光谱的多模二极管激光系统(TMDL-COSPEC-WMS),在接近室温的1%~30%范围内测量760nm附近的氧气浓度。实验过程中,光被分为两束,分别通过样品池和测量池,两个接收光信号收集包含气体浓度信息后送回后台处理,通过测量信号与参考信号之间的相关性和比值反演氧气浓度,采用相关光谱谐波检测技术提高系统的稳定性和信噪比。结果表明,测量得到的氧气浓度与实际浓度值之间存在良好的线性关系。在1个大气压下检测限为280pmm.m,对同一样品进行了验证。在大约30分钟内对环境空气中的氧气进行连续测量,标准偏差为0.056%,证实了系统的稳定性和性能。该系统的软硬件设计能够满足氧气在线监测的需求。实验装置简单易用,便于在复杂环境中应用。