Laboratory of Environmental Engineering, Department of Civil Engineering and Computer Science Engineering, University of Rome "Tor Vergata", Via del Politecnico 1, 00133 Rome, Italy.
Laboratory of Environmental Engineering, Department of Civil Engineering and Computer Science Engineering, University of Rome "Tor Vergata", Via del Politecnico 1, 00133 Rome, Italy.
Waste Manag. 2016 Jan;47(Pt B):195-205. doi: 10.1016/j.wasman.2015.07.018. Epub 2015 Aug 1.
This work assessed the quality in terms of solid recovered fuel (SRF) definitions of the dry light flow (until now indicated as refuse derived fuel, RDF), heavy rejects and stabilisation rejects, produced by two mechanical biological treatment plants of Rome (Italy). SRF classification and specifications were evaluated first on the basis of RDF historical characterisation methods and data and then applying the sampling and analytical methods laid down by the recently issued SRF standards. The results showed that the dry light flow presented a worst SRF class in terms of net calorific value applying the new methods compared to that obtained from RDF historical data (4 instead of 3). This lead to incompliance with end of waste criteria established by Italian legislation for SRF use as co-fuel in cement kilns and power plants. Furthermore, the metal contents of the dry light flow obtained applying SRF current methods proved to be considerably higher (although still meeting SRF specifications) compared to those resulting from historical data retrieved with RDF standard methods. These differences were not related to a decrease in the quality of the dry light flow produced in the mechanical-biological treatment plants but rather to the different sampling procedures set by the former RDF and current SRF standards. In particular, the shredding of the sample before quartering established by the latter methods ensures that also the finest waste fractions, characterised by higher moisture and metal contents, are included in the sample to be analysed, therefore affecting the composition and net calorific value of the waste. As for the reject flows, on the basis of their SRF classification and specification parameters, it was found that combined with the dry light flow they may present similar if not the same class codes as the latter alone, thus indicating that these material flows could be also treated in combustion plants instead of landfilled. In conclusion, the introduction of SRF definitions, classification and specification procedures, while not necessarily leading to an upgrade of the waste as co-fuel in cement kilns and power plants, may anyhow provide new possibilities for energy recovery from waste by increasing the types of mechanically treated waste flows that may be thermally treated.
本研究评估了来自罗马两家机械生物处理厂的干轻料流(迄今被归类为垃圾衍生燃料,RDF)、重质废料和稳定废料的固体回收燃料(SRF)定义方面的质量。首先,根据 RDF 历史特性化方法和数据评估了 SRF 分类和规格,然后应用新发布的 SRF 标准中规定的采样和分析方法。结果表明,与从 RDF 历史数据获得的结果相比(4 级而不是 3 级),新方法应用于干轻料流时,其净热值最差,属于 SRF 较差的等级。这导致其不符合意大利立法规定的作为水泥窑和发电厂共燃物的 SRF 废物末端标准。此外,应用当前 SRF 方法获得的干轻料流的金属含量与根据 RDF 标准方法从历史数据中获得的金属含量相比明显更高(尽管仍符合 SRF 规格)。这些差异与机械生物处理厂生产的干轻料流质量下降无关,而是与 RDF 和当前 SRF 标准设定的不同采样程序有关。特别是,后者方法规定的在四分法之前对样品进行切碎操作,可确保将水分和金属含量更高的最细废料部分也包含在要分析的样品中,从而影响废物的组成和净热值。至于废料流,根据其 SRF 分类和规格参数,发现将其与干轻料流结合使用时,它们可能具有与后者相同的类别代码,甚至可能具有相同的类别代码,这表明这些物料流也可以在燃烧厂中处理,而不是在垃圾填埋场中处理。总之,虽然 SRF 定义、分类和规格程序的引入不一定会导致废物作为水泥窑和发电厂的共燃物升级,但无论如何,通过增加可进行热处理的机械处理废料流的类型,为废物的能源回收提供了新的可能性。