两种具有混合簇次级构筑单元和二氧化碳吸附选择性的基于纳米笼的金属有机框架材料。
Two nanocage-based metal-organic frameworks with mixed-cluster SBUs and CO2 sorption selectivity.
作者信息
Liu Bo, Wu Wei-Ping, Hou Lei, Li Zhi-Sen, Wang Yao-Yu
机构信息
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University , Xi'an 710069, P. R. China.
Institute of Functional Materials, College of Chemistry and Pharmaceutical Engineering, Sichuan University of Science & Engineering , Zigong 643000, P. R. China.
出版信息
Inorg Chem. 2015 Sep 21;54(18):8937-42. doi: 10.1021/acs.inorgchem.5b00987. Epub 2015 Sep 10.
Two nanocage-based metal-organic frameworks respectively built on two and three types of clusters with diisophthalate ligand were constructed, displaying unprecedented (3,4,6)-connected nets, unusual nanocages, and new bipaddle-wheel tetranuclear cluster, as well as highly selective CO2 capture.
构建了两种分别基于两种和三种类型簇且带有间苯二甲酸酯配体的基于纳米笼的金属有机框架，其展现出前所未有的（3,4,6）连接网络、不同寻常的纳米笼和新型双桨轮四核簇，以及对二氧化碳的高选择性捕获。
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