Otto-von-Guericke-University, Institute of Instrumental and Environmental Technology Department of Systems Engineering and Plant Safety, Universitätsplatz 2, 39106 Magdeburg, Germany.
Otto-von-Guericke-University, Institute of Instrumental and Environmental Technology Department of Systems Engineering and Plant Safety, Universitätsplatz 2, 39106 Magdeburg, Germany.
J Hazard Mater. 2016 Jan 15;301:314-26. doi: 10.1016/j.jhazmat.2015.09.006. Epub 2015 Sep 7.
Investigations on the minimum ignition temperatures (MIT) of hybrid mixtures of dusts with gases or solvents were performed in the modified Godbert-Greenwald (GG) furnace. Five combustible dusts and six flammable gases (three ideal and three real) were used. The test protocol was according to EN 50281-2-1 for dust-air mixtures whereas in the case of gases, solvents and hybrid mixtures this standard was used with slight modification. The experimental results demonstrated a significant decrease of the MIT of gas, solvent or dust and an increase in the likelihood of explosion when a small amount of dust, which was either below the minimum explosion concentration or not ignitable by itself, was mixed with gas and vice versa. For example, the MIT of toluene decreased from 540°C to 455°C when small amount of lycopodium was added. It was also confirmed that a hybrid mixture explosion is possible even when both dust and vapour or gas concentrations are respectively lower than their minimum explosion concentration (MEC) and lower explosion limit (LEL). Another example is CN4, the MEC of which of 304 g/m(3) decreased to 37 g/m(3) when propane was added, even though the concentrations of the gas was below its LEL.
在改良的 Godbert-Greenwald(GG)炉中进行了粉尘与气体或溶剂的混合混合物的最低点火温度(MIT)的研究。使用了五种可燃粉尘和六种可燃气体(三种理想气体和三种实际气体)。测试协议符合粉尘-空气混合物的 EN 50281-2-1 标准,而对于气体、溶剂和混合混合物,则使用该标准进行了轻微修改。实验结果表明,当少量粉尘(低于最小爆炸浓度或本身不可燃)与气体混合时,气体、溶剂或粉尘的 MIT 显著降低,爆炸的可能性增加,反之亦然。例如,当加入少量的石松粉时,甲苯的 MIT 从 540°C 降低到 455°C。还证实,即使粉尘和蒸气或气体的浓度分别低于其最小爆炸浓度(MEC)和爆炸下限(LEL),混合混合物爆炸也是可能的。另一个例子是 CN4,其 MEC 为 304 g/m³,当添加丙烷时,降至 37 g/m³,尽管气体浓度低于其 LEL。