Crystal structure of (1R,2S,4R,7R,8S,9R)-3,3-dichloro-8,9-epoxy-4,8,12,12-tetramethyltricyclo[5.5.0.0(2,4)]dodecane.

作者信息

Benzalim Ahmed, Auhmani Aziz, Ait Itto My Youssef, Daran Jean-Claude, Auhmani Abdelwahed

机构信息

Laboratoire de Physico-Chimie Moléculaire et Synthèse Organique, Département de Chimie, Faculté des Sciences Semlalia, BP 2390, Marrakech 40001, Morocco.

Laboratoire de Chimie de Coordination, 205 route de Narbonne, 31077 Toulouse, Cedex 04, France.

出版信息

Acta Crystallogr E Crystallogr Commun. 2015 Jul 4;71(Pt 8):o538-9. doi: 10.1107/S205698901501244X. eCollection 2015 Aug 1.

DOI:10.1107/S205698901501244X

PMID:26396785

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4571385/

Abstract

The title compound, C16H24Cl2O, is built up from two fused six- and seven-membered rings which bear a di-chloro-cyclo-propane group and an ep-oxy group, respectively. In the mol-ecule, the six-membered ring adopts an envelope configuration with the C atom linking the ep-oxy ring at the flap, while the seven-membered ring adopts a boat-sofa conformation.

摘要

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02a4/4571385/f2acf1262db3/e-71-0o538-fig1.jpg

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本文引用的文献

(1S,3S,8R,9S,10R)-9,10-Ep-oxy-3,7,7,10-tetra-methyl-tri-cyclo-[6.4.0.0(1,3)]dodeca-ne.

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Use of intensity quotients and differences in absolute structure refinement.

Acta Crystallogr B Struct Sci Cryst Eng Mater. 2013 Jun;69(Pt 3):249-59. doi: 10.1107/S2052519213010014. Epub 2013 May 17.

(1S,3R,8R,9R,10S)-2,2-Dibromo-3,7,7,10-tetra-methyl-9β,10β-ep-oxy-3,7,7,10-tetra-methyl-tricyclo-[6.4.0.0(1,3)]dodeca-ne.

Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 9;69(Pt 4):o521-2. doi: 10.1107/S1600536813006077. Print 2013 Apr 1.

(1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetra-methyl-9,10-ep-oxy-tricyclo-[6.4.0.0]dodeca-ne.

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(1S,3R,8S,9S,10R)-2,2-Dichloro-9,10-epoxy-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]dodecane and (1S,3R,8S,10R)-2,2-dichloro-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]dodecan-9-one.

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