Choi Hong Dae, Lee Uk
Department of Chemistry, Dongeui University, San 24 Kaya-dong, Busanjin-gu, Busan 614-714, Republic of Korea.
Department of Chemistry, Pukyong National University, 599-1 Daeyeon 3-dong, Nam-gu, Busan 608-737, Republic of Korea.
Acta Crystallogr E Crystallogr Commun. 2015 Jul 31;71(Pt 8):o621-2. doi: 10.1107/S2056989015013948. eCollection 2015 Aug 1.
In the title compound, C15H10ClFO2S, the dihedral angle between the mean planes of the benzo-furan ring [r.m.s. deviation = 0.007 (1) Å] and the 2-fluoro-phenyl ring is 32.53 (5)°. In the crystal, mol-ecules related by inversion are paired into dimers via two different C-H⋯O hydrogen bonds. Further, Cl⋯O halogen bonds [3.114 (1) Å], and F⋯π [F-to-furan-centroid distance = 3.109 (1) Å] and S⋯F [3.1984 (9) Å] inter-actions link these into a three-dimensional network.
在标题化合物C₁₅H₁₀ClFO₂S中，苯并呋喃环平均平面[r.m.s.偏差 = 0.007 (1) Å]与2-氟苯基环之间的二面角为32.53 (5)°。在晶体中，通过两个不同的C—H⋯O氢键，通过倒反相关的分子成对形成二聚体。此外，Cl⋯O卤键[3.114 (1) Å]、F⋯π [F到呋喃质心距离 = 3.109 (1) Å]和S⋯F [3.1984 (9) Å]相互作用将它们连接成三维网络。
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