Distinct Packings of Supramolecular Building Blocks in Metal-Organic Frameworks Based on Imidazoledicarboxylic Acid.

作者信息

Pang Qingqing, Tu Binbin, Ning Erlong, Li Qiaowei, Zhao Dongyuan

机构信息

Department of Chemistry, ‡Laboratory of Advanced Materials, and §iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University , Shanghai 200433, P. R. China.

出版信息

Inorg Chem. 2015 Oct 19;54(20):9678-80. doi: 10.1021/acs.inorgchem.5b01659. Epub 2015 Sep 30.

DOI:10.1021/acs.inorgchem.5b01659

PMID:26421500

Abstract

When the supramolecular building block packings (face-centered, body-centered, and primitive cubic) with different interactions (hydrogen and coordination bonding) were controlled, four new structures based on octahedral M(II) (M = Zn, Ni, Mn) and imidazoledicarboxylate were constructed. The interaction modes between the supramolecular building blocks affect the water stability of the structures. Furthermore, with uncoordinated carboxylate O atoms in the structures, these compounds demonstrate a strong capability of capturing metal ions in the solution.

摘要