Forján R, Asensio V, Rodríguez-Vila A, Covelo E F
Department of Plant Biology and Soil Science, Faculty of Biology, University of Vigo, As Lagoas-Marcosende, 36310, Vigo, Pontevedra, Spain.
Department of Plant Nutrition, CENA, University of São Paulo (CENA-USP), Av. Centenário 303, 13400-970, Piracicaba, SP, Brazil.
Environ Sci Pollut Res Int. 2016 Feb;23(3):2595-602. doi: 10.1007/s11356-015-5489-0. Epub 2015 Oct 3.
One technique applied to restore degraded or contaminated soils is to use amendments made of different types of waste materials, which in turn may contain metals such as Cu, Pb and Zn. For this reason, it is important to determine the capacity of the soil to retain these materials, and to compare the sorption capacity between an amended soil and another unamended soil. The aim of this study was to determine the mobility and availability of these metals in the soil after applying the amendment, and how it affected the soil's sorption capacity. Sorption isotherms were compared with the empirical models of Langmuir and Freundlich to estimate the sorption capacity. The overall capacity of the soils to sorb Cu, Pb or Zn was evaluated as the slope Kr. The amendments used in this study were a mixture made of compost and biochar in different proportions (20, 40, 60, 100 %), which were applied to the mine tailing from a settling pond from a copper mine. The mine tailing that were amended with the mixture of compost and biochar had a higher sorption capacity than the mine tailing from the unamended pond, and their sorption isotherms had a greater affinity towards Cu, Pb and Zn than the mine tailing that was studied. Therefore, the results obtained show that adding a mixture of compost and biochar favours the retention of Cu, Pb and Zn in mine tailing.
一种用于修复退化或受污染土壤的技术是使用由不同类型废料制成的改良剂,而这些废料可能含有铜、铅和锌等金属。因此,确定土壤保留这些物质的能力,并比较改良土壤和未改良土壤之间的吸附能力非常重要。本研究的目的是确定施用改良剂后这些金属在土壤中的迁移性和有效性,以及它如何影响土壤的吸附能力。将吸附等温线与朗缪尔和弗伦德利希的经验模型进行比较,以估计吸附能力。将土壤对铜、铅或锌的总体吸附能力评估为斜率Kr。本研究中使用的改良剂是由不同比例(20%、40%、60%、100%)的堆肥和生物炭制成的混合物,将其施用于某铜矿沉淀池的尾矿。用堆肥和生物炭混合物改良的尾矿比未改良池塘的尾矿具有更高的吸附能力,并且它们的吸附等温线对铜、铅和锌的亲和力比所研究的尾矿更大。因此,所获得的结果表明,添加堆肥和生物炭的混合物有利于尾矿中铜、铅和锌的保留。