College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University , Shandong 250014, China.
Nano Lett. 2015 Nov 11;15(11):7199-203. doi: 10.1021/acs.nanolett.5b01581. Epub 2015 Oct 8.
An IR-driven photocatalytic water splitting system based on WO2-NaxWO3 (x > 0.25) hybrid conductor materials was established for the first time; this system can be directly applied in seawater. The WO2-NaxWO3 (x > 0.25) hybrid conductor material was readily prepared by a high-temperature reduction process of semiconductor NaxWO3 (x < 0.25) nanowire bundles. A novel ladder-type carrier transfer process is suggested for the established IR-driven photocatalytic water splitting system.
首次建立了基于 WO2-NaxWO3(x>0.25)混合导体材料的 IR 驱动光催化水分解系统,该系统可直接应用于海水。WO2-NaxWO3(x>0.25)混合导体材料是通过半导体 NaxWO3(x<0.25)纳米线束的高温还原过程制备的。为所建立的 IR 驱动光催化水分解系统提出了一种新颖的梯型载流子传输过程。