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以L-半胱氨酸为双功能试剂制备的氮硫共掺杂多孔碳球用于高性能锂硫电池。

N and S co-doped porous carbon spheres prepared using L-cysteine as a dual functional agent for high-performance lithium-sulfur batteries.

作者信息

Niu Shuzhang, Lv Wei, Zhou Guangmin, He Yanbing, Li Baohua, Yang Quan-Hong, Kang Feiyu

机构信息

Engineering Laboratory for Functionalized Carbon Materials and Shenzhen Key Laboratory for Graphene-based Materials, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China.

Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China.

出版信息

Chem Commun (Camb). 2015 Dec 28;51(100):17720-3. doi: 10.1039/c5cc07226c.

Abstract

Nitrogen and sulfur co-doped porous carbon spheres (NS-PCSs) were prepared using L-cysteine to control the structure and functionalization during the hydrothermal reaction of glucose and the subsequent activation process. As the sulfur hosts in Li-S batteries, NS-PCSs combine strong physical confinement and surface chemical interaction to improve the affinity of polysulfides to the carbon matrix.

摘要

采用L-半胱氨酸制备了氮硫共掺杂多孔碳球(NS-PCSs),以在葡萄糖水热反应及后续活化过程中控制结构和功能化。作为锂硫电池中的硫载体,NS-PCSs结合了强大的物理限制和表面化学相互作用,以提高多硫化物与碳基体的亲和力。

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