Smith Geoffrey M T, Burton Paul M, Bray Christopher D
Department of Chemistry, Queen Mary University of London, Mile End Road, London, E1 4NS (UK).
Syngenta, Jealott's Hill International Research Centre, Bracknell, Berkshire, RG42 6EY (UK).
Angew Chem Int Ed Engl. 2015 Dec 7;54(50):15236-40. doi: 10.1002/anie.201508467. Epub 2015 Oct 27.
The development of the homologous Julia-Kocienski reaction has led to the discovery of two new reaction modes of epoxides with sulfones. These pathways allow rapid and direct access to a range of γ-sultones and γ-sultines.
同源的Julia-Kocienski反应的发展促成了环氧化合物与砜的两种新反应模式的发现。这些反应途径使得能够快速直接地获得一系列γ-磺酸内酯和γ-磺酸亚胺。
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