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含煤衍生石墨烯量子点的发光聚合物复合薄膜。

Luminescent Polymer Composite Films Containing Coal-Derived Graphene Quantum Dots.

机构信息

Department of Chemistry, ∥Department of Materials Science and NanoEngineering, and †Smalley Institute for Nanoscale Science and Technology, Rice University , 6100 Main Street, Houston, Texas 77005, United States.

出版信息

ACS Appl Mater Interfaces. 2015 Dec 2;7(47):26063-8. doi: 10.1021/acsami.5b06057. Epub 2015 Nov 17.

Abstract

Luminescent polymer composite materials, based on poly(vinyl alcohol) (PVA), as a matrix polymer and graphene quantum dots (GQDs) derived from coal, were prepared by casting from aqueous solutions. The coal-derived GQDs impart fluorescent properties to the polymer matrix, and the fabricated composite films exhibit solid state fluorescence. Optical, thermal, and fluorescent properties of the PVA/GQD nanocomposites have been studied. High optical transparency of the composite films (78 to 91%) and excellent dispersion of the nanoparticles are observed at GQD concentrations from 1 to 5 wt %. The maximum intensity of materials photoluminescence has been achieved at 10 wt % GQD content. These materials could be used in light emitting diodes (LEDs), flexible electronic displays, and other optoelectronic applications.

摘要

基于聚乙烯醇(PVA)的发光聚合物复合材料作为基质聚合物和源自煤的石墨烯量子点(GQDs),通过水溶液浇铸法制备而成。煤衍生的 GQDs 赋予聚合物基质荧光性质,并且所制备的复合膜表现出固态荧光。研究了 PVA/GQD 纳米复合材料的光学、热学和荧光性质。在 GQD 浓度为 1 至 5wt%时,观察到复合膜具有高光学透明度(78 至 91%)和纳米颗粒的优异分散性。在 GQD 含量为 10wt%时,材料的光致发光强度达到最大值。这些材料可用于发光二极管(LED)、柔性电子显示器和其他光电应用。

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