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纳米沸石分散的丙烯酰胺光聚合物中全息传感光谱强度的增强。

Enhancement of spectrum strength in holographic sensing in nanozeolites dispersed acrylamide photopolymer.

作者信息

Yu Dan, Liu Hongpeng, Mao Dongyao, Geng Yaohui, Wang Weibo, Sun Liping, Lv Jiang

出版信息

Opt Express. 2015 Nov 2;23(22):29113-26. doi: 10.1364/OE.23.029113.

Abstract

Holographic sensing of organic vapor is characterized at transmission and reflection geometries in ZSM-5 nanozeolites dispersed acrylamide photopolymer. Nano-zeolites as absorption medium are dispersed into the polymer to enhance the absorptivity to organic vapor. Obvious enhancements of spectrum strength are observed during the sensing process. Two primary factors causing the enhancement, absorption of nanozeolites and photopolymerization induced by broadband white light, are analyzed experimentally. Significant increment provides a quick and intuitive identification strategy for holographic sensing. Accompanying with the wavelength blue-shift, the shrinkage of sample is measured quantitatively under homogeneous white light. It is further demonstrated that the significance of nanozeolites absorption. Finally a theoretical model with mutual diffusion is used to simulate the swelling process. This study provides significant foundation for the application of holographic sensor.

摘要

在分散有丙烯酰胺光聚合物的ZSM - 5纳米沸石中,对有机蒸汽的全息传感在透射和反射几何结构下进行了表征。作为吸收介质的纳米沸石被分散到聚合物中,以增强对有机蒸汽的吸收率。在传感过程中观察到光谱强度有明显增强。通过实验分析了导致增强的两个主要因素,即纳米沸石的吸收和宽带白光诱导的光聚合。显著的增量为全息传感提供了一种快速直观的识别策略。伴随着波长蓝移,在均匀白光下对样品的收缩进行了定量测量。进一步证明了纳米沸石吸收的重要性。最后使用一个相互扩散的理论模型来模拟膨胀过程。这项研究为全息传感器的应用提供了重要基础。

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